Consequences of Limescale
Some types of calcium and salts in water settle and accumulate in equipment and pipes. Factors that accelerate the accumulation of scale are changes in temperature, changes in pressure and whirlpools in the water. Scale is not harmful to health but it destroys valuable equipment and causes problems in pipes.
Scale problems are measured according to the degree of hardness in the water (a product of the calcium and magnesium in the water). Experts claim that levels higher than 250 ppm are destructive to equipment and plumbing.
Limescale is the hard, off-white, chalky deposit found in kettles, hot-water boilers and the inside of inadequately maintained hot-water central heating systems. Also found as a similar deposit on the inner surface of old pipes and surfaces where ‘hard water’ has evaporated.
These types of limescale differ slightly due to their origins. The type found deposited on the heating elements of water heaters etc. has a main component of calcium carbonate, precipitated out of the (hot) water. Hard water contains calcium (and often magnesium) bicarbonate and/or similar salts.
Calcium bicarbonate is soluble in water, however at temperatures above 70 °C the soluble bicarbonate is converted to poorly-soluble carbonate, leading to deposits in places where water is heated.
Corrosion has many serious economic, health, safety, technological, and cultural consequences to our society.
Consequences of Bacteria and Algae
A bacterium (plural: bacteria) is a unicellular microorganism. Typically a few micrometers in length, individual bacteria have a wide-range of shapes, ranging from spheres to rods to spirals. Bacteria are ubiquitous in every habitat on Earth, growing in soil, acidic hot springs, radioactive waste, seawater, and deep in the Earth’s crust. There are typically 40 million bacterial cells in a gram of soil and a million bacterial cells in a milliliter of fresh water; in all, there are approximately five nonillion (5×10-3rd) bacteria in the world, forming much of the world’s biomass.
Bacteria are vital in recycling nutrients, and many important steps in nutrient cycles depend on bacteria, such as the fixation of nitrogen from the atmosphere. However, most of these bacteria have not been characterized, and only about half of the phyla of bacteria have species that can be cultured in the laboratory. The study of bacteria is known as bacteriology, a branch of microbiology.
There are approximately ten times as many bacterial cells as human cells in the human body, with large numbers of bacteria on the skin and in the digestive tract. Although the vast majority of these bacteria are rendered harmless or beneficial by the protective effects of the immune system, a few pathogenic bacteria cause infectious
diseases, including cholera, syphilis, anthrax, leprosy and bubonic plague.
The most common fatal bacterial diseases are respiratory infections, with tuberculosis alone killing about 2 million people a year, mostly in sub-Saharan Africa.
In developed countries, antibiotics are used to treat bacterial infections and in various agricultural processes, so antibiotic resistance is becoming common. In industry, bacteria are important in processes such as wastewater treatment, the production of cheese and yoghurt, and the manufacture of antibiotics and other chemicals. Bacteria are prokaryotes. Unlike cells of animals and other eukaryotes, bacterial cells do not contain a nucleus and rarely harbor membrane-bound organelles. Although the term bacteria traditionally included all prokaryotes, the scientific classification changed after the discovery in the 1990s that prokaryotic life consists of two very different groups of organisms that evolved independently from an ancient common ancestor. These evolutionary domains are called Bacteria and Archaea.
The consequences of Bacteria in applications where Hydropath Technology can be effective in combating the problem.
Bacteria causing disease in cooling towers
and swimming pools.
Bio fouling of heat exchangers
in power stations,
condensers, and cooling towers, and sea water heat exchangers.
Increasing energy requirement.
Increase maintenance requirement due to blockage of filters.
Considerable increase of anti bio fouling chemicals causing damage to the environment.
Algae are a large and diverse group of simple plant-like organisms, ranging from unicellular to multicellular forms. The largest and most complex marine forms are called seaweeds.
They are considered ‘plant-like’ because of their photosynthetic ability, and ‘simple’ because they lack the distinct organs of higher plants such as leaves and vascular tissue. Though the prokaryotic Cyanobacteria (commonly referred to as Blue-green algae) were traditionally included as ‘algae’ in older textbooks, many modern sources regard this as outdated and restrict the term algae to eukaryotic organisms. All true algae therefore have a nucleus enclosed within a membrane and chloroplasts bound in one or more membranes. Algae constitute a paraphyletic and polyphyletic group: they do not represent a single evolutionary direction or line, but a level or grade of organization that may have developed several times in the early history of life on Earth.
Algae lack leaves, roots, and other organs that characterize higher plants. They are distinguished from protozoa in that they are photosynthetic. Many are photoautotrophic, although some groups contain members that are mixotrophic, deriving energy both from photosynthesis and uptake of organic carbon either by osmotrophy, myzotrophy, or phagotrophy. Some unicellular species rely entirely on external energy sources and have reduced or lost their photosynthetic apparatus.
All algae have photosynthetic machinery ultimately derived from the cyanobacteria, and so produce oxygen as a byproduct of photosynthesis, unlike other photosynthetic bacteria such as purple and green sulfur bacteria.
Consequences of Corrosion
Scale causes wasted electricity and gas because heating elements are ineffective. Scale promotes the use of chemicals to remove accumulation on tiles and sinks, and in kettles.
Scale causes repeated malfunctions of expensive household appliances like washing machines and water heaters.
Local boiling “hot spots” can also occur when water
is heated, resulting in the concentration and deposition of salts from the water. Calcium cations from hard water can also combine with soap, which would normally dissolve in soft water. This combination often forms scum which precipitates out in a thin film on the interior surfaces of baths, sinks, and drainage pipes. Soap usually contains salts of anions from neutralized fatty acids or similar chemical compounds. The calcium salts of these anions are less soluble in water.
The type found on air-dried cooking utensils, dripping taps and bathroom tiling consists of calcium carbonate mixed with all the other salts that had been dissolved in the water, prior to evaporation.
Studies in a number of countries have attempted to determine the national cost of corrosion. The most extensive of these studies was the one carried out in the United States in 1976 which found that the overall annual cost of metallic corrosion to the U.S. economy was $70 billion, or 4.2% of the gross national product. To get a feeling for the seriousness of this loss, we may compare it to another economic impact everyone is worried about – the importation of foreign crude oil, which cost $45 billion in 1977.
Recent years have seen an increasing use of metal prosthetic devices in the body, such as pins, plates, hip joints, pacemakers, and other implants. New alloys and better techniques of implantation have been developed, but corrosion continues to create problems. Examples include failures through broken connections in pacemakers, inflammation caused by corrosion products in the tissue around implants, and fracture of weight-bearing prosthetic devices.
An example of the latter is the use of metallic hip joints, which can alleviate some of the problems of arthritic hips. The situation has improved in recent years, so that hip joints which were was at first limited to persons over 60 are now being used in younger persons, because they will last longer.
An even more significant problem is corrosion of structures, which can result in severe injuries or even loss of life. Safety is compromised by corrosion contributing to failures of bridges, aircraft, automobiles, gas pipelines etc. – the whole complex of metal structures and devices that make up the modern world.
The economic consequences of corrosion affect technology. A great deal of the development of new technology is held back by corrosion problems because materials are required to withstand, in many cases simultaneously, higher temperatures, higher pressures, and more highly corrosive environments. Corrosion problems that are less difficult to solve affect solar energy systems, which require alloys to withstand hot circulating heat transfer fluids for long periods of time, and geothermal systems, which require materials to withstand highly concentrated solutions of corrosive salts at high temperatures and pressures. Another example, the drilling for oil in the sea and on land, involves overcoming such corrosion problems as sulfide stress corrosion, microbiological corrosion, and the vast array of difficulties involved in working in the highly corrosive marine environment. In many of these instances, corrosion is a limiting factor preventing the development of economically or even technologically workable systems.
International concern was aroused by the disclosure of the serious deterioration of the artistically and culturally significant gilded bronze statues in Venice, Italy. Corrosive processes will accelerate the deterioration of precious artifacts such as those in Venice by the highly polluted environments that now are prevalent in most of the countries of the world.Likewise, inside the world’s museums conservators and restorers labor to protect cultural treasures against the ravages of corrosion or to remove its traces from artistically or culturally important artifacts.
Aluminium sulphate, written as Al2(SO4)3 or Al2O12S3, is a widely used industrial chemical. It is sometimes incorrectly referred to as alum, as it is closely related to this group of compounds. It occurs naturally as the mineral alunogenite. It is frequently used as a flocculating agent in the purification of drinking water and waste water treatment plants, and also in paper manufacturing.
Aluminium sulfate is rarely, if ever, encountered as the anhydrous salt. It forms a number of different hydrates, of which the hexadecahydrate
Al2(SO4)3•16H2O and octadecahydrate Al2(SO4)3•18H2O are the most common. It can also be very effective as a molluscicide, killing spanish slugs.
Recent research suggests aluminum sulfate may contribute to dementia and Alzheimer’s disease. http://en.wikipedia.org/wiki/Aluminium_sulfate
Aluminium sulphate may be made by dissolving aluminium hydroxide,
Al(OH)3, in sulfuric acid, H2SO4:
2Al(OH)3 + 3H2SO4+ 3H2O ? Al2(SO4)3·6H2O
Aluminium Sulphate is used in water purification and as a mordant dyeing and printing textiles. In water purification, it causes impurities to coagulate which are removed as the particulate settles to the bottom of the container or more easily filtered. This process is called coagulation or flocculation.
When dissolved in a large amount of neutral or slightly-alkaline water, aluminium sulphate produces a gelatinous precipitate of aluminium hydroxide, Al(OH)3. In dyeing and printing cloth, the gelatinous precipitate helps the dye adhere to the clothing fibres by rendering the pigment insoluble.
Due to its name, it has been linked to the legendary Camelot, and even Camlann, but historians have been quick to refute these suggestions.
The town elected two members to the Unreformed House of Commons. It was considered a rotten borough and its franchise was abolished in 1832.
In July 1988, the water supply to the town and the surrounding area was contaminated when 20 tons of aluminium sulphate was poured into the wrong tank at the nearby Lowermoor water works on Bodmin Moor near Bodmin.
An independent inquiry into the incident (the worst of its kind in British history) was started in 2002, and a draft report issued in January 2005, but questions still remain as to the long-term effects on the health of local residents.
Michael Meacher, who visited Camelford in his post as environment minister, was said to have called the incident and its aftermath, ‘A most unbelievable scandal.’